basic knowledge of conductometry titrations and its principle, instrumentation, & advantages and disdavantages of these titrations. Conductometry DR. . 3Principle The main principle involved in this method is that the movement of the ions creates the electrical. Conductometry-. Introduction. Ohm’s law. Conductometric measurements. Factor affecting conductivity. Application of conductometry. tometric titration.

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Then the conductivity of the solution is measured by the following equation: The temperature is maintained constant with the help of the thermostat.

Initially the plot shows the decrease in the conductivity and then shows the increase in the conductivity. In this method, the two end points are observed.

Used in the determination of the ionic product of the water. Initially the addition of the silver nitrate to the potassium chloride shows the stability in the conductivity and the excess of the silver nitrate addition increases the conductivity because of the formation of the single precipitate.

Size of the ions: This type cell is mainly used for the measurement of the low conductance. From Wikipedia, the free encyclopedia. For example, titrations of the strong acid such as HCL with the weak base such as the ammonium hydroxide.

In this method, the decrease in the hydrogen ions concentration shows the decrease in conductomrtry conductivity at the end point.

It was also around this time when Willis Whitney, who was studying the interactions of sulfuric acid and chromium sulfate complexes, found the first conductometric endpoint. Conductometry free pharmacy study material pharmaceutical analysis pharmaceutical analysis lecture notes.



Scallan, The determination of strong and weak acidic groups in sulfite pulps, Svensk Paperstidn. All these are operated by the battery. There are mainly three types of cells used as conductivity cells: Less satisfactory when compared to other methods. The solutions are compulsory diluted conductomegry the measurements. Explain the concept of cell constant. What are the different methods of conductivity measurements?

2. Conductometry – Pharmaceutical Analysis [Book]

On passing the current, chloroplatinic acid under goes electrolysis and the electrodes are blackened. The hydrogen ions show sharp decrease in the conductivity. The conductometric titration curve is a plot of the measured conductance or conductivity values as a function of the volume of the NaOH solution added. By using this site, you agree to the Terms of Use and Privacy Policy. This shows the decrease in the conductivity.

Weak conducttometry with weak base titration curve.

To avoid the polarisation effect, these electrodes are coated with the platinum black. January Learn how and when to remove this template message. This replacement of the ions with the other ions shows the conductance increase or decrease.

Conductometry – Wikipedia

The titration of the potassium chloride with the mercuric chlorate. In this type, the cell is dipped in the sample solution to measure the conductance in the titrations. Labels Conductometry free pharmacy conducgometry material pharmaceutical analysis pharmaceutical analysis lecture notes. Potassium chloride is titrated with the precipitating agent such as the silver nitrate solution. Vorlander first proposed the non-aqueous titration method that is titration of aniline with the HCl in non-aqueous solvent, that is, benzene.


The reaction mechanism was first proposed by Peter Griessin.

The plot between the conductivity and the volume of the titrant shows the plateau. Nehmat Sandhu 10 November at Look up conductometry in Wiktionary, the free dictionary. The steps involved in the non-aqueous titrimetric method are proposed by the Tomicek.

Then the plot between the conductivity and the volume of the titrant shows the plateau. Strong acid conductomery weak base: These are carried out as same as the acid—base titrations by using non-aqueous solvents.

This article needs additional citations for verification. Cell constant is defined as the conductivity of the cell: Then the cell is connected to the resistor box R and the alternating current is passed through the cell with the help of induction coil.

These are commonly employed by dipping in the analyte solution.

Pharmaceutical Analysis by P. D. Chaithanya Sudha

No need for the specific conductivity. What are the different types of conductometric titrations? This is because of pricniple ions mobility by increasing the temperature.